Product ID:PR-894-S,PART A,ALL COLORS
MSDS Date:04/13/1989
FSC:8010
NIIN:00N011180
MSDS Number: BJJWK

PRODUCTS RESEARCH & CHEMICAL CORPORATION

5430 SAN FERNANDO ROAD
GLENDALE, CA 91209

Emergency Phone: 800-228-5635

Info Phone: 818-240-2060

Cage: DO563

PRODUCTS RESEARCH & CHEMICAL

1800 GLENDALE, CA 91209 US

Telephone: 818-240-2060

Cage: DO563

4.6

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 30%

OSHA PEL N/K

ACGIH TLV: N/K

POLYETHER POLYOL POLYMER (POLYURETHANE PREPOLYMER)

CAS: 9057-91-4

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENEDIISOCYANATE (MIXED ISOMERS) (SARA III)

CAS: 26471-62-5

RTECS: NQ9490000

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGESTION:POSSIBLE CORROSIVE ACTION IN
THE MOUTH,STOMACH TISSUE AND DIGESTIVE TRACT.
Explanation of Carcinogenicity:TOLUENE DIISOCYANATE:INAD EVID FOR CARC
IN HUMANS;SUFF EVID FOR CARC IN ANIMALS (IARC,1987).SUSP HUMAN
CARC/(SEE SUPP)
Effects of Overexposure:EYES:IRRIT,WATERING,POSS REVERSIBLE CORNEAL
DMG.SKIN:LOCAL IRRIT,DISCOLORATION.ALLERGIC RASH POSS IF
SENSITIZED.INGEST:IRRIT,POSS CORR IN MOUTH,STOM TISSUE,DIGESTIVE
TRACT.INHAL:NOSE,THROAT,LUNG,EYE I RRIT;WATERING EYES,SORE
THROAT,CHEST TIGHTNESS,POSS BREATHING DIFFICULTY.ASTHMA-LIKE
SYMPTOMS IN SENSITIZED INDIVIDUALS.
Medical Cond Aggravated by Exposure:INDIVIDUALS SUFFERING FROM ASTHMA
OR OTHER CHRONIC RESPIRATORY CONDITIONS MAY EXHIBIT A HEIGHTENED
SENSITIVITY TO ISOCYANATES & SHOULD AVOID INHAL EXPOSURE.MAY CAUSE
ALLERGIC RASH IF SENSITIZED.

First Aid:EYES:FLUSH W/ LUKEWARM WATER FOR AT LEAST 15 MIN.CONSULT
PHYSICIAN.SKIN:WASH THOROUGHLY W/ SOAP & WATER.CONSULT A
PHYSICIAN.DISCARD/DECONTAMINATE CLOTHING/SHOES BEFORE
REUSE.INGESTION:DO NOT INDUCE VO MITING.GIVE MILK OR WATER TO
DRINK.CONSULT A PHYSICIAN.INHALATION:REMOVE TO FRESH AIR,IF NOT
BREATHING GIVE ARTIFICIAL RESPIRATION.IF BREATHING IS DIFFICULT
GIVE OXYGEN.CONSULT A PHYSICIAN.

Flash Point Method:PMCC
Flash Point:118F,48C
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:FOAM,CO*2,DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .USE WATER TO COOL HEAT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE
BUILDUP IN CLOSED CONTAINERS.HAZARDOUS DECOMPOSITION
PRODUCTS:OXIDES OF CARBON,NITROGEN,& POSS TRACES OF HCN.

Spill Release Procedures:WEAR AIR-SUPPLIED RESPIRATOR FOR MAJOR
UNVENTILATED SPILLS.COVER W/ ABSORBENT MATL,ADD DECONTAM SOLUTION
(5% CONC AMMONIA,2% DETERGENT,93% WATER) & ALLOW TO REACT 10
MIN.COLLECT IN CONTR,ADD ADDITIONA L DECONTAM SOLUTION & KEEP
LOOSELY COVERED 48 HRS.
Neutralizing Agent:N/K

Handling and Storage Precautions:N/K
Other Precautions:AVOID MOISTURE CONTAMINATION WHICH WILL CAUSE CO*2
PRESSURE.DO NOT RESEAL CONTAINERS IF MOISTURE CONTAMINATION IS
SUSPECTED.AVOID INGESTION.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:SOLVENT RESISTANT
Eye Protection:CHEM WORK GOGG,FACESHLD OPTIONAL .
Other Protective Equipment:N/K
Work Hygienic Practices:DISCARD OR DECONTAMINATE CONTAMINATED CLOTHING
AND SHOES BEFORE REUSE.
Supplemental Safety and Health
EXPLAN OF CARCIN:KNOWN ANIMAL CARC (NTP,1989).KNOWN TO CAUSE CANCER
(CAL PROP 65,1989).ROUTES OF ENTRY:INGESTION/INHALATION/SKIN .

Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Density:N/K
Spec Gravity:1.13 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:APPRECIABLE
Appearance and Odor:N/K

Stability Indicator/Materials to Avoid:YES
WATER,ALCOHOLS,STRONG BASES,AMINES.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:OXIDES OF CARBON,NITROGEN,AND POSSIBLE
TRACES OF HCN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .D001 EPA HAZARDOUS WASTE
NUMBER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.